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Unsymmetrical porphyrins: the role of meso-substituents on their physical properties

César A. Henriques

Department of Chemistry, University of Coimbra, Rua Larga, 3004-535 Coimbra, Portugal

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Nuno P.F. Gonçalves

Department of Chemistry, University of Coimbra, Rua Larga, 3004-535 Coimbra, Portugal

Currently at Luzitin, SA, Rua Bayer, São Martinho do Bispo, 3004-535 Coimbra, Portugal

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Artur R. Abreu

Department of Chemistry, University of Coimbra, Rua Larga, 3004-535 Coimbra, Portugal

Currently at Luzitin, SA, Rua Bayer, São Martinho do Bispo, 3004-535 Coimbra, Portugal

Corresponding author

SPP full member in good standing.

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Mário J.F. Calvete

Department of Chemistry, University of Coimbra, Rua Larga, 3004-535 Coimbra, Portugal

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and

Mariette M. Pereira

Department of Chemistry, University of Coimbra, Rua Larga, 3004-535 Coimbra, Portugal

Corresponding author, tel: +351 239854474, fax: +351 239827703.

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https://doi.org/10.1142/S1088424612500332Cited by:17

Abstract

The synthesis of one-step meso-porphyrins type A_xB_y containing alkyl and pyridyl groups is described. An initial assess of the amphiphilic proprieties were determined by its log K_ow using fluorescence detection techniques and values from 1.42 to 2.15 were observed. The melting points of this set of porphyrins was determined and a strong effect of the number and size of the meso-alkyl chain is ascribed.

Keywords:

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History

Received 2 December 2011

Accepted 4 January 2012
Keywords
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Unsymmetrical porphyrins: the role of meso-substituents on their physical properties

Abstract

References

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